Accent wall ideas: which wall, which color

The accent wall is the one your eye lands on from the doorway. Usually that is the wall behind the sofa or the bed, and almost never a wall with a window in it. Paint it two to four shades deeper than the other walls, or commit to a genuine color: deep green, ink blue, or oxblood. The failure mode is timidity: an accent wall one shade off the others reads like a painting mistake.
Choosing the wall
Pick the wall the room already points at. In living rooms that is the wall behind the main seating; in bedrooms, behind the headboard; in dining rooms, the wall facing the entry. Avoid walls broken up by windows and doors, where the color gets chopped into fragments and loses its authority. A chimney breast or an alcove wall is a gift, since architecture already frames it.
Colors that earn the wall
Deep greens are the current workhorse: calm and deliberate at once against white trim and oak floors. Ink and navy blues do the same in cooler rooms. Terracotta and oxblood warm a north-facing room without shrinking it. If the rest of the room is already colorful, the accent can be a deeper cut of a color you own: the green of the plants, the rust in the rug.
Whatever the color, keep the other three walls genuinely quiet (warm white or the palest version of the accent) and let trim stay crisp. The accent works because of the contrast, and muddying the supporting walls halves the effect.

Preview before you commit the weekend
An accent wall is the perfect visualizer use case because the stakes are asymmetric: one wall, strong color, high regret potential. Photograph the room, assign the candidate color to just that wall (Repaint’s surface list includes "Accent Wall" as its own target), and render. You will know in a minute whether the green that looked commanding on Pinterest survives your actual sofa.
Questions
Can an accent wall be a light color?
Yes, when the other walls are darker; a pale wall in a deep-toned room reads as intentional. What fails is a light accent against slightly-less-light walls; the contrast is too weak to register as a choice.
Should trim on the accent wall match the walls or the room?
Match the room’s trim color. Continuous trim ties the accent wall into the architecture; painting trim to match the accent color makes the wall float like a sticker.